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Thus, the effectively replenished photothermal effect is responsible for greatly ameliorating the slow kinetics of photocatalytic hydrogen evolution with the apparent activation energy reduction from 49.6 kJ mol −1 to 32.2 kJ mol −1, and the NiCo 2S 4/ZnIn 2S 4 photocatalyst achieves a hydrogen evolution rate of 19654.0 μmol g −1 h −1 under visible and NIR light irradiation with an apparent quantum efficiency of 56.7% at 400 nm.
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